Simultaneous stabilization/solidification of arsenic in acidic wastewater and tin mine tailings with synthetic multiple solid waste base geopolymer

Stabilization/Solidification (S/S) is considered as a feasible technology for the treatment of arsenic (As) in acidic wastewater (AW) and tin mine tailings (TMTs); however, high cost, high carbon footprint, and strict reaction conditions are the main limitations. Herein, a novel alkali-activated geopolymer material (AAGM) for S/S As was synthesized by combining AW, TMT, gypsum (GP), and metakaolin (MK). At room temperature, an initial As concentration of 3914 mg/L, a NaOH content of 4.98%, and an MK content of 20% decreased the As leaching concentration to 1.55 mg/L (<5 mg/L). The main S/S mechanisms of As included physical encapsulation of C-(A)-S-H and geopolymer structures, ion exchange of ettringite, and formation of Fe–As and Ca–As precipitates. Further studies showed that increasing initial As concentration and MK content facilitated the formation of Ca–As precipitates and C–(A)–S–H gels. The semi-dynamic leaching tests revealed that the leaching mechanism of As was surface wash-off. The effective diffusion coefficients of the samples were less than 10 −13  cm 2 /s, and the respective leachability indexes were greater than 9, indicating that AAGM was effective in preventing the leaching of As. Therefore, this study provides a green and low cost solution for the synergistic utilization of AW, TMT, GP, and MK.