Engineering of a wafer-shaped titanium-based catalyst of TiO 2 /MIL-125(Ti)@Ti 3 C 2 for enhanced Fenton-like degradation of Congo red: Optimization, mechanistic study, and reusability
Journal of Industrial and Engineering Chemistry, ISSN: 1226-086X, Vol: 143, Page: 704-716
2025
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Findings on Engineering Reported by Investigators at Qassim University [Engineering of a Wafer-shaped Titanium-based Catalyst of Tio2/mil-125(Ti) @ti3c2 for Enhanced Fenton-like Degradation of Congo Red: Optimization, Mechanistic Study, and ...]
2025 APR 01 (NewsRx) -- By a News Reporter-Staff News Editor at Middle East Daily -- Data detailed on Engineering have been presented. According to
Article Description
A titanium-based Fenton-like heterogeneous catalyst was synthesized from titanium dioxide (TiO 2 ), MIL-125(Ti), and Ti 3 C 2 MXene for degrading the notorious Congo red (CR). The successful combination of the titanium components was assured by bountiful characterization apparatuses. Optimization of the conditions for the Fenton-like degradation of CR dye was performed by studying the impact of the pH and temperature of the catalytic system, the dosage of TiO 2 /MIL-125(Ti)@Ti 3 C 2, the concentrations of hydrogen peroxide (H 2 O 2 ) and CR, and the mass ratio between the catalyst’s components. A kinetic study was executed on the degradation of CR and H 2 O 2 during a reaction time of 60 min using First-order and Second-order models. The degradation pathway of CR by TiO 2 /MIL-125(Ti)@Ti 3 C 2 was investigated by the scavenging test. Additionally, Adsorption and catalytic degradation mechanisms were explored using X-Ray Photoelectron Spectroscopy (XPS) analysis. The cycling test proceeded on TiO 2 /MIL-125(Ti)@Ti 3 C 2 for five succeeding Fenton-like degradation runs of CR dye. Ultimately, the Ti-based heterogeneous catalyst exhibited superior adsorption and Fenton-like degradation performance toward the anionic dye with a good recyclability feature.
Bibliographic Details
Elsevier BV
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