Effectual binding of gallic acid with p-sulfonatocalix[4]arene: An experimental and theoretical interpretation
Journal of Luminescence, ISSN: 0022-2313, Vol: 196, Page: 392-398
2018
- 8Citations
- 12Captures
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Article Description
The host-guest interaction of gallic acid (GA) with p-sulfonatocalix[4]arene (p-SC4) is studied using emission and excited state lifetime techniques. The quenching effect on the emission intensity and excited state lifetime is observed upon binding. The impact of oxidation potential upon binding is studied using cyclic voltammetric technique. The structural features and the mode of binding of GA with p-SC4 is examined using 1 H NMR and rotating frame overhauser effect spectroscopy (ROESY) techniques. The binding of GA with p-SC4 has also been examined by means of density functional theory simulations. The calculated interaction energy of GA with p-SC4 (22.15 kcal/mol) indicates the strong binding nature.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0022231317314394; http://dx.doi.org/10.1016/j.jlumin.2017.12.063; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85043316068&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0022231317314394; https://dx.doi.org/10.1016/j.jlumin.2017.12.063
Elsevier BV
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