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Magneto-optical and high-frequency electron paramagnetic resonance spectroscopy of Er 3+ ions in CaMoO 4 single crystal

Journal of Luminescence, ISSN: 0022-2313, Vol: 270, Page: 120564
2024
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Article Description

We present the optical and magneto-optical spectroscopy and electron paramagnetic resonance (EPR) investigations of CaMoO 4 single crystals doped with the erbium ions. Telecom-wavelength resonance transition inhomogeneous line width of Er 3+ is relatively narrow for oxide crystals which makes this material promising for quantum technologies applications. The hyperfine structure in optical spectra of 167 Er 3+ isotope is well resolved. Energies and symmetries of wavefunctions of 39 energy levels of Er 3+ ions in the crystal-field (CF) of S 4 symmetry and g-factors of some CF Kramers doublets were measured and successfully simulated on the basis of CF calculations. The obtained set of CF parameters was used for modeling the hyperfine structure profiles observed in the optical absorption spectra.

Bibliographic Details

K. I. Gerasimov; M. M. Minnegaliev; S. A. Moiseev; E. I. Baibekov; B. Z. Malkin; G. S. Shakurov; R. B. Zaripov; A. V. Lebedev

Elsevier BV

Biochemistry, Genetics and Molecular Biology; Physics and Astronomy; Chemistry

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