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On the vibrational assignment in the ground electronic state of NO 3

Journal of Molecular Spectroscopy, ISSN: 0022-2852, Vol: 314, Page: 73-78
2015
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Article Description

The vibration–rotational structure of the ground A 2 ′ state of the NO 3 radical is re-considered, because Hirota (2015) presented an objection to the vibrational assignment of our previous papers (Kawaguchi et al., 2011, 2013; Fujimori et al., 2013). The present study examines the vibrational assignment in the following points, (1) laser induced fluorescence (LIF) spectra observed by Fukushima and Ishiwata in the 1050 cm −1 region, (2) Fourier transform (FT) spectra of vibrational bands from the v 4 = 1 state, and a diode laser spectrum of the 2 ν 4 band. These considerations support our previous assignments, that is, ν 3 + ν 4 = 1492 cm −1 and ν 3 = 1055 cm −1 for 14 NO 3.

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