The effect of high-level waste glass composition on spinel liquidus temperature
Journal of Non-Crystalline Solids, ISSN: 0022-3093, Vol: 384, Page: 32-40
2014
- 21Citations
- 20Captures
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Article Description
Spinel crystals precipitate in high-level waste glasses containing Fe, Cr, Ni, Mn, Zn, and Ru. The liquidus temperature ( TL ) of spinel as the primary crystallization phase is a function of glass composition, and the spinel solubility ( c 0 ) is a function of both glass composition and temperature ( T ). Previously reported models of TL as a function of composition are based on TL measured directly, which requires laborious experimental procedures. Viewing the curve of c 0 versus T as the liquidus line allows a significant broadening of the composition region for model fitting. This paper estimates TL as a function of composition based on c 0 data obtained with the X-ray diffraction technique.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0022309313000963; http://dx.doi.org/10.1016/j.jnoncrysol.2013.02.014; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84890127491&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0022309313000963; https://dx.doi.org/10.1016/j.jnoncrysol.2013.02.014
Elsevier BV
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