Nanosized starlike molecules. Synthesis and optical properties of 2,4,6-tris(disilanylenebithienylene)-1,3,5-triazine derivatives
Journal of Organometallic Chemistry, ISSN: 0022-328X, Vol: 702, Page: 67-72
2012
- 14Citations
- 9Captures
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Article Description
Starlike molecules ( 5 ) and ( 7 ) that have a triazine unit as a core and arms consisting of an alterative arrangement of an Si–Si bond and bithienylene unit were prepared by the Pd-catalyzed reactions of 2,4,6-tris[5-(1,3-dioxa-4,4,5,5-tetramethyl-2-borolanyl)-2-thienyl]triazine with 5-bromothienylpentamethyldisilane and with 1-(5-bromothienyl)-2-bithienyltetramethyldisilane, respectively. In the UV–vis absorption and fluorescence spectra, 5 and 7 showed absorption maxima in a range of 398–399 nm, and revealed higher fluorescence quantum yields than that of 2,4,6-tris(bithienyl)triazine.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0022328X11008102; http://dx.doi.org/10.1016/j.jorganchem.2011.12.029; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84856371839&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0022328X11008102; https://dx.doi.org/10.1016/j.jorganchem.2011.12.029
Elsevier BV
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