Very strong trans effect in ruthenacyclic carbamoyl complexes leads to ligand redistribution in phosphine derivatives
Journal of Organometallic Chemistry, ISSN: 0022-328X, Vol: 887, Page: 5-11
2019
- 3Citations
- 7Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
The ruthenacyclic carbamoyl complexes [Ru (2-NHC(O)C 5 H 4 N) (CO) 2 (X) (NCMe)] (X = Cl, Br) ( 1 ) and [Ru (2-NHC(O)C 5 H 4 N) (CO) 2 (2-S-Py)] ( 2 ) undergo substitution reactions with organophosphines to afford derivatives which are prone to a redistribution of the phosphine ligand. We have studied these redistribution reactions experimentally and computationally, and proposed an essentially common reaction pathway. The results suggest that the carbamoyl ligand exerts a very strong trans effect.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0022328X19300774; http://dx.doi.org/10.1016/j.jorganchem.2019.02.022; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85062443816&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0022328X19300774; https://dx.doi.org/10.1016/j.jorganchem.2019.02.022
Elsevier BV
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