Influence of atmospheric conditions on the formation and structural properties of two-dimensional SbSI films
Materials Letters, ISSN: 0167-577X, Vol: 357, Page: 135682
2024
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Article Description
Two-dimensional heavy pnictogen chalcohalides, such as SbSI, SbSeI, and BiSI, are promising materials for solar energy harvesting (SEH) devices. In this paper, we report the influence of atmospheric conditions on the formation and structural properties of SbSI films fabricated under N 2 and air atmospheres using a modified two-step method. Under N 2 atmosphere, a preferentially (1 2 1)-oriented SbSI film without impurities formed. In contrast, under air atmosphere, a film with mixed crystalline phases of SbSI and secondary Sb 2 O 3 formed. The Sb 2 O 3 phase could be reduced by applying excess sulfur. These results provide a fundamental step toward optimizing the properties of chalcohalides for SEH device applications.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0167577X23018670; http://dx.doi.org/10.1016/j.matlet.2023.135682; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85178579280&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0167577X23018670; https://dx.doi.org/10.1016/j.matlet.2023.135682
Elsevier BV
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