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Dipole polymer-coated crystalline grains to endure temperature variations of perovskite photovoltaics

Matter, ISSN: 2590-2385, Vol: 6, Issue: 4, Page: 1063-1065
2023
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For practical applications, perovskite photovoltaics must deal with stability issues to endure temperature variations because of the phase transition tendency under thermal lattice strain. In recent work published in Science, an ordered dipolar polymer β-poly(1,1-difluoroethylene) was adopted to coat perovskite crystalline grains and align energy levels to endure temperature variations of p-i-n perovskite solar cells. Power conversion efficiency was boosted to 24.6% over 18 mm 2 and 23.1% over 1 cm 2 with no sign of fatigue, showing high operational stability under rapid thermal cycling variations between −60°C and +80°C.

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