Solar-driven nitrogen fixation with bio-inspired Mo/Sr-MOFs photocatalysts at ambient conditions
Molecular Catalysis, ISSN: 2468-8231, Vol: 552, Page: 113676
2024
- 14Citations
- 7Captures
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Article Description
Photocatalytic reduction of nitrogen to ammonia has attracted much attention recently because ammonia stands out as one of the indispensable chemicals on a global scale. Herein, bio-inspired MOFs Mo-NTC and Sr-NTC were designed and synthesized by using Mo or Sr as metal nodes and 1,4,5,8-naphthalenetetracarboxylic acid (H 4 NTC) as ligands which has visible-light responsiveness. The best photocatalytic nitrogen fixation performance of Sr-NTC was about 143.10 μmol·g −1 ·h −1 which is higher than Mo-NTC (70.20 μmol·g −1 ·h −1 ). The ability of Sr-NTC to convert nitrogen to ammonia was verified by 15 N 2 isotope labeling experiment and in-situ FTIR measurement. Various characterization methods were employed to confirm the enhanced performance of photocatalytic nitrogen reduction. This work provides a new idea for applying metal Sr and Mo and organic ligand to construct photocatalysis to fix nitrogen driven by solar at ambient conditions.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S2468823123007599; http://dx.doi.org/10.1016/j.mcat.2023.113676; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85176942636&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S2468823123007599; https://dx.doi.org/10.1016/j.mcat.2023.113676
Elsevier BV
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