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Water splitting at an anion-exchange membrane as studied by impedance spectroscopy

Journal of Membrane Science, ISSN: 0376-7388, Vol: 496, Page: 78-83
2015
  • 53
    Citations
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  • 112
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Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    53
    • Citation Indexes
      53
  • Captures
    112

Article Description

Electrochemical impedance spectroscopy (EIS) is largely used in studying water splitting reaction in bipolar membranes (BPMs). This reaction is also very important in monopolar membrane systems, where it constitutes one of the possible mechanisms of the overlimiting current conductance. However, despite of 60-year research history in this domain, there are only a few studies where EIS was applied. Apparently, it is due to poor understanding of AC response of monopolar membranes in overlimiting current range where charge transfer by electrodiffusion competes with current-induced convection and water splitting products transfer.

Bibliographic Details

Ekaterina Kniaginicheva; Natalia Pismenskaya; Stanislav Melnikov; Ekaterina Belashova; Philippe Sistat; Marc Cretin; Victor Nikonenko

Elsevier BV

Biochemistry, Genetics and Molecular Biology; Materials Science; Chemistry; Chemical Engineering

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