One-pot efficient Heck coupling in water catalyzed by palladium nanoparticles tethered into mesoporous organic polymer
Journal of Molecular Catalysis A: Chemical, ISSN: 1381-1169, Vol: 350, Issue: 1, Page: 40-48
2011
- 74Citations
- 24Captures
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Article Description
A new palladium grafted mesoporous organic polymer catalyst has been synthesized through the reaction of palladium(II) acetate with mesoporous poly-triallylamine (MPTA-1) in methanol. Powder XRD, HR TEM, FE SEM-EDS, AAS, UV–vis spectroscopic tools are employed to characterize this supported palladium catalyst Pd–MPTA-1. The Heck coupling reactions between a series of aryl halides and alkenes have afforded the corresponding C–C coupling products in good yield over this Pd-catalyst using water as reaction medium. This protocol provides a simple strategy for the generation of a variety of new C–C bonds by using this recyclable heterogeneous catalyst under environmentally benign conditions.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S1381116911003578; http://dx.doi.org/10.1016/j.molcata.2011.09.002; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=80054923437&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S1381116911003578; https://dx.doi.org/10.1016/j.molcata.2011.09.002
Elsevier BV
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