Oxidation of olefins with H 2 O 2 catalyzed by gallium(III) nitrate and aluminum(III) nitrate in solution
Journal of Molecular Catalysis A: Chemical, ISSN: 1381-1169, Vol: 422, Page: 216-220
2016
- 14Citations
- 24Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
Soluble gallium and aluminum nitrates (simple salts of non-transition metals) are good catalysts for the epoxidation of olefins (cyclooctene, dec-1-ene) including terpenes (carvone, limonene) with hydrogen peroxide in ethyl acetate or tetrahydrofurane (THF). Typically, the gallium salt is more efficient in comparison with the aluminum derivative. Products are formed in yields up to 93%, turnover numbers (TONs) attained 40. Addition of trifluoroacetic acid or pyrazine-2-carboxylic acid (PCA) accelerates the reaction and improves the yield. In striking contrast, added 2,2′-bipyridine or phenanthroline dramatically inhibit the oxidation.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S1381116916300711; http://dx.doi.org/10.1016/j.molcata.2016.03.004; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85028260839&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S1381116916300711; https://dx.doi.org/10.1016/j.molcata.2016.03.004
Elsevier BV
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