Electrochemical behavior of lead, silver and bismuth containing alloys in the KCl-PbCl 2 melt
Journal of Molecular Liquids, ISSN: 0167-7322, Vol: 361, Page: 119619
2022
- 3Citations
- 9Captures
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Article Description
The anode dissolution of ternary Pb-Ag-Bi metallic alloys with different components concentration has been studied in the molten KCl-PbCl 2 eutectics. A lead dissolution was found to be the main process in the Pb-Ag-Bi (60.0–15.0–25.0), Pb-Ag-Bi (42.9–21.4–35.7), Pb-Ag-Bi (7.0–34.9–58.1) alloys within the whole interval of studied anode current densities. The Pb-Ag-Bi ((4.8–35.7–59.5) and Pb-Ag-Bi ((2.4–36.6–61.0) alloys at the anode current densities of 2.3 A/cm 2 and 0.14 A/cm 2 have the limiting diffusion current of lead dissolution. At the anode current densities exceeding the aforesaid values a bismuth dissolution takes place. The number of electrons participating in each electrode reaction is determined for each mechanism of metal electrodissolution. A regime of electrochemical separation of lead alloys is chosen based on the analysis of polarization curves. Metallic lead and Ag-Bi-Pb (5.1 wt%) alloy were obtained in the laboratory electrolytic cell.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0167732222011576; http://dx.doi.org/10.1016/j.molliq.2022.119619; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85132748203&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0167732222011576; https://dx.doi.org/10.1016/j.molliq.2022.119619
Elsevier BV
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