Mn(I)-based photoCORMs for trackable, visible light-induced CO release and photocytotoxicity to cancer cells
Polyhedron, ISSN: 0277-5387, Vol: 172, Page: 125-131
2019
- 28Citations
- 25Captures
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Article Description
Four new Mn(I)–carbonyl complexes of general formula, [Mn(L)(CO) 3 ] ( 1 – 4 ) where L = 2-(benzo[d]thiazol-2-yl)phenol (L 1 ), 2-(benzo[d]thiazol-2-yl)-4,6-di-tert-butylphenol (L 2 ), 2-(2-hydroxyphenyl)-3H-anthra[1,2- d ]imidazole-6,11-dione (L 3 ) and 2-(3,5-di-tert-butyl-2-hydroxyphenyl)-3H-anthra[1,2- d ]imidazole-6,11-dione (L 4 ) rapidly release CO cooperatively on activation with visible light accompanied by a visual change in luminescence properties of the complexes allowing us to track photo-activated CO release in HeLa cells. CO-induced photocytotoxicity by the complexes was also studied in HeLa cells. Photo-activated CO release and mechanism was spectroscopically and theoretically probed. Overall, Mn(I)–carbonyls with theranostics properties are potentially emerged as the next-generation photo-theranostics.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0277538719302475; http://dx.doi.org/10.1016/j.poly.2019.04.008; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85065046172&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0277538719302475; https://dx.doi.org/10.1016/j.poly.2019.04.008
Elsevier BV
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