The case of [(bpm)Re(CO) 3 Br] and anti -[Br(CO) 3 Re(μ-bpm)Re(CO) 3 Br] (bpm: 2,2′-bipyrimidine) towards multi-metallic Re I species and their properties

The reaction of [Re(CO) 3 (THF)Br] 2 and 2,2′-bipyrimidine (bpm) in dichloromethane at room temperature employing a stoichiometric 2:1 ratio leads to a mixture of [(bpm)Re(CO)3Br] (21%) and anti-[Br(CO)3Re( μ-bpm)Re(CO)3Br] (79%). When a 1:1 ratio is used, only anti-[Br(CO)3Re( μ-bpm)Re(CO)3Br] is obtained in a 89% yield. The reaction of [Re(CO) 5 Br] and (bpm) leads to [(bpm)Re(CO)3Br ] as a single product. [(bpm)Re(CO)3Br] and anti-[Br(CO)3Re( μ-bpm)Re(CO)3Br] display one and two rhenium(I) centers of distorted octahedral coordination geometry respectively, each with a facial ligand correlation. The intramolecular metal to metal distance is 5.8508(16) Å in anti-[Br(CO)3Re( μ-bpm)Re(CO)3Br]. The HOMO-LUMO gap for [(bpm)Re(CO)3Br] results 0.74 eV larger (3.03 vs 2.29 eV) than the computed for anti-[Br(CO)3Re( μ-bpm)Re(CO)3Br]. In the same sense, the anti-isomer is computed to be 0.14 eV (13.4 kJ mol −1 ) more stable compared to the hypothetical syn-[Br(CO)3Re( μ-bpm)Re(CO)3Br]. Cyclic voltammetry shows that the difference between the Re I /Re 0 reduction and its Re I /Re II oxidation in terms of potential is about 3.46 V for [(bpm)Re(CO)3Br ], while this value diminishes to 2.62 V for anti-[Br(CO)3Re( μ-bpm)Re(CO)3Br]. Following this tendency, the MLCT band for [(bpm)Re(CO)3Br] is centered at 385 nm (DMF), while it is red-shifted almost 100 nm for anti-[Br(CO)3Re( μ-bpm)Re(CO)3Br]. While [(bpm)Re(CO)3Br ] emits at 680 nm (excited at 380 nm), anti-[Br(CO)3Re( μ-bpm)Re(CO)3Br] remains non-emissive, which is attributed to a favored vibrational deactivation path.