Thiol-ene-clickable and emissive carbazole-based polymer networks with tunable colors
Reactive and Functional Polymers, ISSN: 1381-5148, Vol: 106, Page: 17-23
2016
- 4Citations
- 14Captures
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Article Description
Band gap tuning and processability of organic materials are significant topics for both scientific research and commercial applications. In this study, we synthesized a series of main chain cross-linkable polymers by thiol-ene click chemistry from N-allyl carbazole and different heterocycles via conventional Suzuki coupling polymerization reaction. The emission color of polymers could be successfully tuned from blue to red by attaching different benzazole-acceptor moieties to the carbazole donor unit. We also investigated the effects of cross-linking with respect to the amount of pentaerythritol tetrakis(3-mercaptopropionate) cross-linker on the optical, electrochemical, and surface morphological properties of the polymer films. The results showed that these polymers can be used as emissive active layers in solution-processable multilayer organic light-emitting diodes.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S1381514816301341; http://dx.doi.org/10.1016/j.reactfunctpolym.2016.07.003; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84978286911&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S1381514816301341; https://api.elsevier.com/content/article/PII:S1381514816301341?httpAccept=text/xml; https://api.elsevier.com/content/article/PII:S1381514816301341?httpAccept=text/plain; https://dx.doi.org/10.1016/j.reactfunctpolym.2016.07.003
Elsevier BV
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