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Allene–alkyne cross-coupling for stereoselective synthesis of substituted 1,4-dienes and cross-conjugated trienes

Tetrahedron, ISSN: 0040-4020, Vol: 64, Issue: 16, Page: 3437-3445
2008
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Article Description

Titanium-mediated cross-coupling of allenic alcohols with alkynes has been investigated. Divergent reaction pathways were discovered that provide either stereodefined 1,4-dienes or substituted cross-conjugated trienes. In short, allene substitution plays a critical role in the determination of reaction pathway.

Bibliographic Details

Shimp, Heidi L; Hare, Alissa; McLaughlin, Martin; Micalizio, Glenn C

Elsevier BV

Biochemistry, Genetics and Molecular Biology; Pharmacology, Toxicology and Pharmaceutics; Chemistry

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