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Cyclopentadienyl-ruthenium(II) complexes as efficient catalysts for the reduction of carbonyl compounds

Tetrahedron, ISSN: 0040-4020, Vol: 73, Issue: 11, Page: 1511-1516
2017
  • 5
    Citations
  • 0
    Usage
  • 16
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Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    5
    • Citation Indexes
      5
  • Captures
    16

Article Description

This work reports the reduction of a large variety of aldehydes and ketones with the system PhSiH 3 /[CpRu(PPh 3 ) 2 Cl] in good to excellent yields and high chemoselectivity. The catalyst [CpRu(PPh 3 ) 2 Cl] can be used in at least 12 catalytic cycles with excellent catalytic activity and several substrates were reduced under solvent free conditions.

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