Blue light-promoted N–H insertion of amides, isatins, sulfonamides and imides into aryldiazoacetates: Synthesis of unnatural α-aryl amino acid derivatives
Tetrahedron, ISSN: 0040-4020, Vol: 76, Issue: 51, Page: 131316
2020
- 25Citations
- 18Captures
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Article Description
A photochemical protocol using blue light allows the N–H insertion of amides, isatins, sulfonamides and imides into aryldiazoacetates to afford the corresponding α-amino esters. This method is experimentally simple, inexpensive and tolerates numerous functional groups, thus allowing the straightforward preparation of a variety of α-aryl amino acid derivatives in good yields.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0040402020304713; http://dx.doi.org/10.1016/j.tet.2020.131316; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85086948283&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0040402020304713; https://dx.doi.org/10.1016/j.tet.2020.131316
Elsevier BV
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