Diphenyl ethers and depsidones from the endophytic fungus Aspergillus unguis BCC54176
Tetrahedron, ISSN: 0040-4020, Vol: 105, Page: 132612
2022
- 15Citations
- 7Captures
- 1Mentions
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Article Description
Four new diphenyl ethers, aspergillusethers G−J ( 1 – 4 ), and one new depsidone, emeguisin D ( 7 ), together with eighteen known compounds have been isolated and characterized from the endophytic fungus Aspergillus unguis BCC54176. The chemical structures were established based on spectroscopic evidence in conjunction with a chemical transformation. Furthermore, the chemical structure of compound 7 was verified by single-crystal X-ray diffraction data. The isolated compounds were evaluated for biological activity. Compound 7, emeguisin C ( 10 ), and nidulin ( 14 ) showed antibacterial activity against Bacillus cereus with an equal MIC value of 1.56 μg/mL, while emeguisin A ( 8 ), nornidulin ( 13 ), 2-chlorounguinol ( 16 ), and aspergillusidone C ( 21 ) displayed anti-phytopathogenic activity against Colletotrichum acutatum with the equal MIC value of 3.13 μg/mL. Compound 7 was also active against Staphylococcus aureus with an MIC value of 1.56 μg/mL. However, none of the tested compounds had cytotoxicity against cancerous (MCF-7 and NCI–H187) and non-cancerous (Vero) cells.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0040402021009236; http://dx.doi.org/10.1016/j.tet.2021.132612; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85121668732&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0040402021009236; https://dx.doi.org/10.1016/j.tet.2021.132612
Elsevier BV
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