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Activation of silylphosphines by diethyl azodicarboxylate: novel silylation of alcohols

Tetrahedron Letters, ISSN: 0040-4039, Vol: 45, Issue: 7, Page: 1409-1411
2004
  • 29
    Citations
  • 0
    Usage
  • 8
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    29
    • Citation Indexes
      29
  • Captures
    8

Article Description

A novel activation mode of silylphosphines and an application of that to silylation of alcohols were described. Silylphosphines were found to be instantly activated by means of DEAD and PPTS to form reactive silyl cation equivalents. By using the activated species, silylation of alcohols successfully proceeded under mild acidic condition.

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