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Trichlorosilyl triflate for enantioselective direct-type aldol reaction with chiral phosphine oxide

Tetrahedron Letters, ISSN: 0040-4039, Vol: 52, Issue: 22, Page: 2834-2836
2011
  • 35
    Citations
  • 0
    Usage
  • 5
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    35
    • Citation Indexes
      35
  • Captures
    5

Article Description

Trichlorosilyl triflate, in the presence of a chiral Lewis base catalyst, provides an effective method for the enantioselective direct-type aldol reaction of aldehydes and ketones. A chiral Lewis base induces both the production and activation of trichlorosilyl enol ether, yielding an aldol product in good yield and with high diastereo- and enantioselectivities.

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