Trichlorosilyl triflate for enantioselective direct-type aldol reaction with chiral phosphine oxide
Tetrahedron Letters, ISSN: 0040-4039, Vol: 52, Issue: 22, Page: 2834-2836
2011
- 35Citations
- 5Captures
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Article Description
Trichlorosilyl triflate, in the presence of a chiral Lewis base catalyst, provides an effective method for the enantioselective direct-type aldol reaction of aldehydes and ketones. A chiral Lewis base induces both the production and activation of trichlorosilyl enol ether, yielding an aldol product in good yield and with high diastereo- and enantioselectivities.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0040403911004849; http://dx.doi.org/10.1016/j.tetlet.2011.03.095; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=79955560732&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0040403911004849; https://dx.doi.org/10.1016/j.tetlet.2011.03.095
Elsevier BV
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