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Selective Heck reaction of electron-rich aryl bromides with cyclic alkenones

Tetrahedron Letters, ISSN: 0040-4039, Vol: 56, Issue: 14, Page: 1801-1804
2015
  • 17
    Citations
  • 0
    Usage
  • 15
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    17
    • Citation Indexes
      17
  • Captures
    15

Article Description

A simple and efficient protocol for the Heck reaction of cyclic alkenones with electron-rich aryl bromides has been developed. A ligand combination of X-Phos and tri - tert -butylphosphonium hydrogen tetrafluoroborate in the presence of Pd(PPh 3 ) 2 Cl 2 and Na 2 CO 3 in DMSO was found to be efficient and selective for electron-rich aryl bromides with high substrate scope for cyclic alkenones.

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