Di- ortho -C H arylation of phenylalanine: A bimetallic interaction between Pd(IV)-Ag(I)
Tetrahedron Letters, ISSN: 0040-4039, Vol: 74, Page: 153158
2021
- 10Citations
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Article Description
The direct di -ortho -arylation of substituted phenylalanines has been accomplished via methoxyiminoacyl (MIA)-mediated Pd-catalyzed C H functionalization. A diverse array of phenylalanine substrates is amenable to this protocol, providing di -ortho -arylated phenylalanine derivatives with good to high efficiency. Computational results revealed that a bimetallic interaction between Pd(IV)-Ag(I) was formed through the localized orbital, which obviously favored the reductive elimination step of the arylation process.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0040403921003671; http://dx.doi.org/10.1016/j.tetlet.2021.153158; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=85106557499&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0040403921003671; https://dx.doi.org/10.1016/j.tetlet.2021.153158
Elsevier BV
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