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Total synthesis of MS-444: A myosin light chain kinase and HuR inhibitor from Micromonospora sp. KY7123

Tetrahedron Letters, ISSN: 0040-4039, Vol: 80, Page: 153328
2021
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Article Description

MS-444, as a myosin light chain kinase and HuR inhibitor, plays an important role in physiological regulation. An alternative total synthesis of MS-444 is reported by a route incorporating Sonogashira coupling, addition/elimination of allenic sulfonium salts generated in situ and intramolecular Friedel-Crafts acylation. This approach starts from commercially available materials and involves a distinctive method of constructing furan ring. Most of reactions in the route are readily to implement and have the prospect of large-scale application.

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