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Functionalized styrene synthesis via palladium-catalyzed C C cleavage of aryl ketones

Tetrahedron Letters, ISSN: 0040-4039, Vol: 95, Page: 153721
2022
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Article Description

We report herein the synthesis of functionalized styrenes via palladium-catalyzed Suzuki–Miyaura cross-coupling reaction between aryl ketone derivatives and potassium vinyltrifluoroborate. The employment of pyridine-oxazoline ligand was the key to the cleavage of unstrained C C bond. A variety of functional groups and biologically important moleculars were well tolerated. The orthogonal Suzuki–Miyaura coupling demonstrated the synthetic practicability.

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