Different approaches to the determination of ammonium ions at low levels by flow injection analysis
Analytica Chimica Acta, ISSN: 0003-2670, Vol: 214, Issue: C, Page: 121-136
1988
- 91Citations
- 14Captures
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Article Description
Several flow-injection methods are examined critically for their suitability for determing submicromolar levels of ammonium ion on a routine basis. Nesslerization and the Berthelot reaction are not sufficiently sensitive. The gas-diffusion separation is more satisfactory. On the basis of a simple diffusion model, the effects of operating parameters on the ammonium concentration in the acceptor line of the gas-diffusion unit are discussed and experimentally verified. With the optimized gas-diffusion conditions, spectrophotometric detection with an acid-base indicator or the application of a liquid-membrane ammonium-sensitive electrode offers detection limits around 10 −8 mol 1 -1. Carbon dioxide interference in the acid-base indicator method causes problems with baseline stability and long-term drift. A severe limitation on futher enhancement of sensitivity by in-valve preconcentration is the contamination levelof ammonium present in water and reagents. Effective preconcentation (20-fold in 1 min) is obtained by using an ion-exchange microcolumn placed in the injection loop of the valve.
Bibliographic Details
http://www.sciencedirect.com/science/article/pii/S0003267000804353; http://dx.doi.org/10.1016/s0003-2670(00)80435-3; http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0002551135&origin=inward; https://linkinghub.elsevier.com/retrieve/pii/S0003267000804353; https://api.elsevier.com/content/article/PII:S0003267000804353?httpAccept=text/xml; https://api.elsevier.com/content/article/PII:S0003267000804353?httpAccept=text/plain; http://linkinghub.elsevier.com/retrieve/pii/S0003267000804353; http://api.elsevier.com/content/article/PII:S0003267000804353?httpAccept=text/xml; http://api.elsevier.com/content/article/PII:S0003267000804353?httpAccept=text/plain; http://dx.doi.org/10.1016/s0003-2670%2800%2980435-3; https://dx.doi.org/10.1016/s0003-2670%2800%2980435-3
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