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Depletion modulation of Ar–H 2 O in a supersonic planar plasma

Chemical Physics Letters, ISSN: 0009-2614, Vol: 355, Issue: 5, Page: 538-542
2002
  • 23
    Citations
  • 0
    Usage
  • 5
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    23
    • Citation Indexes
      23
  • Captures
    5

Article Description

A sensitive detection technique for tunable diode laser spectroscopy is presented that is suited to study rotationally resolved spectra of weakly bound complexes. The method uses a low energetic plasma source to achieve an efficient concentration modulation in a supersonic planar jet expansion. The method is demonstrated with rotationally resolved spectra of the Π (1 10 )← Σ (1 01 ) and Π (2 12 )← Σ (1 01 ) internal rotation/vibration bands of ortho Ar–H 2 O in the ν 2 bend region of H 2 O. The latter transition has not been reported before and is recorded at 1658.0309(6) cm −1.

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