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How strong are the complexes between methane radical cation and noble gas atoms?

Chemical Physics Letters, ISSN: 0009-2614, Vol: 311, Issue: 3, Page: 281-291
1999
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This article studies the interaction the methane radical cation (C 2v ) with noble gas atoms (He, Ne, Ar, and Kr). A number of stationary points, between 5 and 7, have been located depending on the interacting noble gas atom. MP2, MP4 and CCSD-T computational levels with the 6-311++G(d,p) and 6-311++G(2d,2p) basis sets have been used. The minima show different characteristics depending on the interacting hydrogen atom, similar to hydrogen-bonded or van der Waals complexes. The transition states obtained indicate an easy transfer between the symmetrical and non-symmetrical complexes.

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