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Two-dimensional line-shape analysis of photon-echo signal

Chemical Physics Letters, ISSN: 0009-2614, Vol: 314, Issue: 5, Page: 488-495
1999
  • 52
    Citations
  • 0
    Usage
  • 60
    Captures
  • 0
    Mentions
  • 0
    Social Media
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Metrics Details

  • Citations
    52
    • Citation Indexes
      52
  • Captures
    60

Article Description

We analyze the two-dimensional (2D) line shape obtained by 2D Fourier transforming the time-domain response of a photon-echo signal as a function of the two coherence periods, t 1 and t 3. The line shape obtained for a two-level system with homogeneous and inhomogeneous broadening is shown to be sensitive to the magnitude of both of these line-broadening mechanisms. It is shown that the ellipticity of the 2D line shape can be related to the ratio of homogeneous to inhomogeneous broadening.

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