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The electron beam technique in carbon monoxide

Journal of Electron Spectroscopy and Related Phenomena, ISSN: 0368-2048, Vol: 105, Issue: 2, Page: 239-244
1999
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  • Citations
    3
    • Citation Indexes
      3

Article Description

Electron-induced emissions of the First Negative System of CO + were studied in CO and Ar+CO(10%) free jets. The mechanisms of the excitation–emission process were analysed to make use of the electron beam technique in CO as well as in a CO+Ar mixture. It was shown that more than 85% of the (0,0) band emission was excited by primary electrons. Rate constants of collisional quenching of the CO + (B) state by CO and Ar were measured at low (<200 K) temperatures. The negative temperature dependence of the quenching rates is in qualitative agreement with the results obtained for other molecular ions.

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