The Synthesis of Thiaazacrown Ethers Containing Pyridine as Subuint for the Construction of Ag + -ISEs
International Journal of Electrochemical Science, ISSN: 1452-3981, Vol: 8, Issue: 6, Page: 8544-8556
2013
- 1Citations
- 5Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations1
- Citation Indexes1
- CrossRef1
- Captures5
- Readers5
Article Description
Three new thiaazacrown ethers containing pyridine as subunit were synthesized and charaterized as Ag + -ion selective eslectrodes (Ag + -ISEs) ionophores. Study shows that the ring size and donor number of the ligands have great effect on the selectivity and sensitivity of the synthesized compounds. Potentiometric responses reveal that the ISE based on 2, 2’-thiodiethanethiol derivative exhibits best selectivity toward Ag + relative to other two compounds. The plasticized poly (vinyl chloride) (PVC) membrane electrode using this N 3 S 5 -ligand as ionophore has been characterized in detail. Under optimal conditions, a detection limit of 3.9×10 -7 M Ag + can be obtained for the proposed membrane Ag + -ISE.
Bibliographic Details
Elsevier BV
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