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Shape control of Zn(II) metal-organic frameworks by modulation synthesis and their morphology-dependent catalytic performance

Crystal Growth and Design, ISSN: 1528-7505, Vol: 15, Issue: 5, Page: 2533-2538
2015
  • 78
    Citations
  • 0
    Usage
  • 62
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    78
    • Citation Indexes
      78
  • Captures
    62

Article Description

Micro- and nanorods and plates of three porous Zn(II)-based metal-organic frameworks, [Zn2(oba)2(4-bpdb)]n·2(DMF) (TMU-4), [Zn(oba)(4-bpdh)0.5]n·1.5(DMF) (TMU-5), and [Zn(oba)(4-bpmb)0.5]n 1.5(DMF) (TMU-6) were synthesized by the coordination modulation method. The effects of concentration of modulator, temperature, and time of reaction on size and morphology have been investigated. Also, catalytic performance of TMU-5 nanosized metal-organic framework in Knoevenagel condensation reaction was evaluated.

Bibliographic Details

Mohammad Yaser Masoomi; Saeideh Beheshti; Ali Morsali

American Chemical Society (ACS)

Chemistry; Materials Science; Physics and Astronomy

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