Iron-Catalyzed Reductive Ring-Rearrangement Reaction of Bridged Benzo[b]oxocin-4-ones with Grignard Reagents to Afford Bridged Benzo[b]oxocin-2-ols
Organic Letters, ISSN: 1523-7052, Vol: 27, Issue: 11, Page: 2693-2699
2025
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Article Description
An iron-catalyzed reductive ring-rearrangement reaction of bridged benzo[b]oxocin-4-ones with Grignard reagents to produce bridged benzo[b]oxocin-2-ols is reported. Mechanistic studies indicate that an iron redox catalysis cycle involving oxidative addition to the C-O bond by low-valence iron and β-methoxyl elimination as key steps operates in this reaction.
Bibliographic Details
American Chemical Society (ACS)
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