Lanthanide - Transition-metal complexes: From ion pairs to extended arrays
Accounts of Chemical Research, ISSN: 0001-4842, Vol: 36, Issue: 7, Page: 499-508
2003
- 231Citations
- 43Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations231
- Citation Indexes231
- 231
- CrossRef211
- Captures43
- Readers43
- 43
Article Description
New lanthanide - transition-metal (Ln-M) compounds were prepared and the structural relationships of the metal combinations were discerned. Numerous compounds derived from divalent or trivalent lanthanides and from transition metals in groups 7-11 were isolated. Three different types of interactions were observed: (1) Ln-M direct bonds, (2) ionic associations, and (3) carbonyl or cyanide linkers between the metals. These assorted Ln-M interactions influence the assembly of the compounds, and discrete molecules or polymeric arrays were encountered. The extended arrays spanning one, two, and three dimensions can function as heterogeneous catalyst precursors. Two classes of systems, Ln-M carbonyls and cyanides, are described.
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