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New heterometallic hybrid polymers constructed with aromatic sulfonate-carboxylate ligands: Synthesis, layered structures, and properties

Crystal Growth and Design, ISSN: 1528-7505, Vol: 12, Issue: 5, Page: 2613-2624
2012
  • 45
    Citations
  • 0
    Usage
  • 20
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    45
    • Citation Indexes
      45
  • Captures
    20

Article Description

Three novel alkali metal-cadmium coordination polymers [K Cd(Hsb)(HO)]1, [NaCd(sip)(DMF)(HO)]2, and [NaCd(sip)(DMF)(HO) ]•2nHdeta•2nHO 3 (Hsb = 4-sulfobenzoic acid, Hsip = 5-sulfoisophthalic acid) have been synthesized and characterized by single crystal X-ray diffraction and spectroscopic and thermogravimetric methods. The solid state structure of 1 consists of inorganic layers, formed from NaO and CdO, polyhedral units, bridged via the sulfonate site of the ligand. The layers are pillared by the organic portions of the ligands to form a three-dimensional framework classified as IO. Compounds 2 and 3 display inorganic-organic hybrid layers arranged in 3D via nonspecific (hydrophobic) interactions between the DMF ligands. The two-dimensional frameworks of the layers are classified as IO (in 2) and IO (in 3). The guest diethylammonium ions in 3 are arranged in hydrophobic channels along the [011] crystallographic direction and circumvented by the DMF ligands. © 2012 American Chemical Society.

Bibliographic Details

Teresa Kurc; Józef Hoffmann; Veneta Videnova-Adrabinska; Jan Janczak

American Chemical Society (ACS)

Chemistry; Materials Science; Physics and Astronomy

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