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High oxidation state multiple metal-carbon bonds

Chemical Reviews, ISSN: 0009-2665, Vol: 102, Issue: 1, Page: 145-179
2002
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Article Description

A review of alkylidyne complexes with the more numerous alkylidene complexes is given. The literature is covered from the beginning of 1991 for both alkylidene and alkylidyne complexes. The vast majority of high oxidation state compounds that contain a multiple metal-carbon bond contain Ta, Mo, W, or Re. Nonetheless, the review will include all metals within groups 4-7. Tables of reported alkylidene complexes and alkylidyne complexes serve as quick reference guides to the literature and to location of the compound within the text.

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