Vibrational spectroscopic studies of aqueous interfaces: Salts, acids, bases, and nanodrops
Chemical Reviews, ISSN: 0009-2665, Vol: 106, Issue: 4, Page: 1155-1175
2006
- 396Citations
- 178Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations396
- Citation Indexes396
- 396
- CrossRef394
- Captures178
- Readers178
- 178
Review Description
Spectroscopic studies of surface water structure as it is affected by salts, acids, and ammonia are reviewed. The review also includes clusters that contribute to understanding the aqueous interface along with studies of aqueous nanodrops. The interfacial structure of water is highly sensitive to the addition of ionic inorganic solutes. The effects of monovalent inorganic anions depend on the polarizability of the ion, which is related to ion size: the more polarizable the anion, the stronger the effect. The interfacial concentration gradients give rise to an increasing interfacial depth as well as with the divalent inorganic anion. However, the larger charge on the polarizable sulfate anion drives an ordering of the water molecules well beyond the immediate solvation shell. For acids, dramatic affects are observed for the dangling OH, as well as possible surface potential effects. The surface potential and interfacial depth increase due to concentration gradients extending deeper into the bulk solution. Overall, cluster and aqueous nanodrop studies are found to significantly contribute to unraveling the effect of ions on the surface.
Bibliographic Details
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