Fullerenes in liquid media: An unsettling intrusion into the solution chemistry
Chemical Reviews, ISSN: 0009-2665, Vol: 113, Issue: 7, Page: 5149-5193
2013
- 190Citations
- 142Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations190
- Citation Indexes190
- 190
- CrossRef156
- Captures142
- Readers142
- 142
Review Description
Researchers have made efforts to unify the results in terms of solution chemistry and colloid science of compounds including fullerenes (C ). The most principal thermodynamic property of any compound with respect to solution chemistry is its solubility. A vast collection of solubility values in individual and mixed solvents for fullerenes, specifically C and C has been gathered. The solubility of fullerene molecules in the polar solvents is negligible despite their extremely high polarizability. The enhanced solubility in some nitrogen-containing liquids indicates the possibility of specific solvation or chemical modification of the fullerene molecule, making it worthwhile to regard such solvents as 'reactive' ones. The molar volume of the solid fullerene C is also independent of temperature and as a rule exceeds its partial molar volume in solution.
Bibliographic Details
American Chemical Society (ACS)
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