Synthesis and photochemistry of Ru(II) complexes containing phenanthroline-based ligands with fused pyrrole rings
Inorganic Chemistry, ISSN: 0020-1669, Vol: 41, Issue: 25, Page: 6688-6694
2002
- 27Citations
- 20Captures
Metric Options: Counts1 Year3 YearSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Metrics Details
- Citations27
- Citation Indexes27
- 27
- CrossRef24
- Captures20
- Readers20
- 20
Article Description
Hydrolysis of 1,10-phenanthrolinopyrrole ethyl ester leads to the acid derivative which is unstable at room-temperature releasing CO and forming 1,10-phenanthrolinopyrrole (php). The ligand reacts with ruthenium(II) to form a series of complexes of the general formula [Ru(php)(bpy)], where bpy = 2,2′-bipyridine and n = 1-3. The photochemical properties reveal that the complexes have longer-lived excited states than the standard complex, [Ru(bpy)]. Their emission lifetimes range from 9.04 μs (n = 1) to 35.5 μs (n = 3) at 77 K compared to 7.57 μs for the standard. Similarly, at room-temperature, emission lifetimes range from 1.20 μs (n = 1) to 1.70 μs (n = 3) relative to the standard (0.56 μs). The emission quantum yields also have higher values than the standard [Ru(bpy)] under similar conditions. The temperature-dependent studies for the complexes establish the distribution among the radiative, nonradiative, and MLCT to d-d decay channels and are in agreement with the energy gap law.
Bibliographic Details
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know