Complexes of 2,5-bis(α-pyridyl)pyrrolate with Pd(II) and Pt(II): A monoanionic iso-φ-electron ligand analog of terpyridine
Inorganic Chemistry, ISSN: 0020-1669, Vol: 51, Issue: 19, Page: 10122-10128
2012
- 26Citations
- 26Captures
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Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
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Metrics Details
- Citations26
- Citation Indexes26
- 26
- CrossRef24
- Captures26
- Readers26
- 26
Article Description
Palladium and platinum metal complexes of 2,5-bis(α-pyridyl)- pyrrolate (PDP) are reported and characterized by spectroscopic methods, single-crystal X-ray diffraction, and elemental analysis. The single-crystal X-ray structures of these complexes exhibit structural features indicative of significant φ-backbonding. To illustrate the effect, bond lengths are statistically compared to unmetalated PDP and to a previously reported Zn(II) complex that exhibits no backbonding. Density functional theory calculations are used to aid understanding of the electronic structural basis of the observed phenomena. © 2012 American Chemical Society.
Bibliographic Details
American Chemical Society (ACS)
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