Direct synthesis of ligand-based radicals by the addition of bipyridine to chromium(II) compounds
Inorganic Chemistry, ISSN: 0020-1669, Vol: 52, Issue: 5, Page: 2271-2273
2013
- 13Citations
- 29Captures
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Article Description
The reaction of 2,2′-bipyridine (bpy) with monomeric chromium(II) precursors was used to prepare the S = 1 complexes Cr(tBu-acac)(bpy) (1) and (η-Cp)(η-Cp)Cr(bpy) (3), as well as the S = 2 compound Cr[N(SiMe)](bpy) (4). The crystallographically determined bond lengths indicate that the bpy ligands in 1 and 3 are best regarded as radical anions, while 4 shows no structural evidence for electron transfer from Cr to the neutral bpy ligand. © 2013 American Chemical Society.
Bibliographic Details
American Chemical Society (ACS)
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