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Two isostructural 3D lanthanide coordination networks (Ln = Gd , Dy) with squashed cuboid-type nanoscopic cages showing significant cryogenic magnetic refrigeration and slow magnetic relaxation

Inorganic Chemistry, ISSN: 1520-510X, Vol: 53, Issue: 8, Page: 3926-3928
2014
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Two isostructural lanthanide-based 3D coordination networks [Ln = Gd (1), Dy(2)] with densely packed distorted cuboid nanoscopic cages are reported for the first time. Magnetic characterization reveals that complex 1 shows a significant cryogenic magnetocaloric effect (-ΔS = 44 J kg K), whereas 2 shows slow relaxation of magnetization. © 2014 American Chemical Society.

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