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A novel cyclometalated dimeric iridium complex, [(dfpbo) lr] [dfpbo = 2-(3,5-difluorophenyl)benzoxazolato-N, C], containing an unsupported Ir-Ir bond

Inorganic Chemistry, ISSN: 0020-1669, Vol: 48, Issue: 4, Page: 1263-1265
2009
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Article Description

An unusual iridium complex, [(dfpbo)lr] [dfpbo = 2-(3,5-difluorophenyl)benzoxazolato-N,C], which is the first dimeric iridium complex composed of two bis-cyclometalated Ir structures connected by an unsupported Ir - Ir bond, has been synthesized and fully characterized. Under mild conditions of neutral pH at room temperature, this complex dissociated spontaneously to form the stable radical [lr(dfpbo)]'. © 2009 American Chemical Society.

Bibliographic Details

Lee, Hsiu-Pen; Hsu, Yi-Fen; Chen, Tsun-Ren; Chen, Jhy-Der; Chen, Kelvin H-C; Wang, Ju-Chun

American Chemical Society (ACS)

Chemistry

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