Synthesis and characterization of one-dimensional and molecular M(tren)InAsS (M = Mn, Co, and Zn) compounds with a noncondensed AsS unit
Inorganic Chemistry, ISSN: 0020-1669, Vol: 48, Issue: 17, Page: 8180-8185
2009
- 46Citations
- 6Captures
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Metrics Details
- Citations46
- Citation Indexes46
- 46
- CrossRef38
- Captures6
- Readers6
Article Description
Four transition-metal-amine complexes incorporating indium thioarsenates with the general formula M(tren)InAsS (M=Mn, Co, and Zn) and a noncondensed AsS unit have been prepared and characterized. Single-crystal-X-ray diffraction analyses show that compound 1 (M=Mn) crystallizes in the triclinic crystal system (space group: Pl̄) and consists of a one-dimensional (1 D) inorganic {[InAsS]} cnain ancl [Mn(tren)] groups bonded to the opposite sides of an eight-membered In AsS ring along the backbone of the infinite inorganic chains. Compounds 2 (M=Mn), 3 (M=Zn), and 4 (M=Co) are isomorphous molecular compounds. They all crystallize in the monoclinic crystal system (space group: P2/c). The Mn cation of [Mn(tren)] in 1 has a distorted octahedral environment, while the transition-metal cations of [M(tren)] in the other three compounds locate in trigonal-bipyramidal environments. This difference results in different bonding modes of [M(tren)] to indium thioarsenates between compound 1 and the other three compounds © 2009 American Chemical Society.
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