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Liquid-Phase Hydrogenation of Cinnamaldehyde over a Ru-Sn Sol-Gel Catalyst. 2. Kinetic Modeling

Industrial and Engineering Chemistry Research, ISSN: 0888-5885, Vol: 43, Issue: 9, Page: 2039-2048
2004
  • 10
    Citations
  • 0
    Usage
  • 17
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

  • Citations
    10
    • Citation Indexes
      10
  • Captures
    17

Article Description

Selective liquid-phase hydrogenation of cinnamaldehyde to cinnamyl alcohol over a sol-gel 5% Ru-5% Sn/SiO catalyst has been studied in a stirred batch reactor (373-483 K, 25-70 bar). Experiments provided information about the influence of temperature and pressure on the catalytic performance. The catalyst deactivation in different solvents during repeated experiments has been studied, too. Kinetic modeling based on several reaction mechanisms allowing discrimination between rival models was carried out.

Bibliographic Details

Jan Hájek; Johan Wärnå; Dmitry Yu. Murzin

American Chemical Society (ACS)

Chemistry; Chemical Engineering; Engineering

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