Liquid-Phase Hydrogenation of Cinnamaldehyde over a Ru-Sn Sol-Gel Catalyst. 2. Kinetic Modeling
Industrial and Engineering Chemistry Research, ISSN: 0888-5885, Vol: 43, Issue: 9, Page: 2039-2048
2004
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Article Description
Selective liquid-phase hydrogenation of cinnamaldehyde to cinnamyl alcohol over a sol-gel 5% Ru-5% Sn/SiO catalyst has been studied in a stirred batch reactor (373-483 K, 25-70 bar). Experiments provided information about the influence of temperature and pressure on the catalytic performance. The catalyst deactivation in different solvents during repeated experiments has been studied, too. Kinetic modeling based on several reaction mechanisms allowing discrimination between rival models was carried out.
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