Methyl tert-butyl ether catalytic oxidation over Pt/Rh and Pd monolithic exhaust catalysts: Intrinsic kinetic studies in a spinning basket flow reactor
Industrial and Engineering Chemistry Research, ISSN: 0888-5885, Vol: 40, Issue: 15, Page: 3325-3330
2001
- 4Citations
- 4Captures
Metric Options: CountsSelecting the 1-year or 3-year option will change the metrics count to percentiles, illustrating how an article or review compares to other articles or reviews within the selected time period in the same journal. Selecting the 1-year option compares the metrics against other articles/reviews that were also published in the same calendar year. Selecting the 3-year option compares the metrics against other articles/reviews that were also published in the same calendar year plus the two years prior.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Example: if you select the 1-year option for an article published in 2019 and a metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019. If you select the 3-year option for the same article published in 2019 and the metric category shows 90%, that means that the article or review is performing better than 90% of the other articles/reviews published in that journal in 2019, 2018 and 2017.
Citation Benchmarking is provided by Scopus and SciVal and is different from the metrics context provided by PlumX Metrics.
Article Description
Kinetic studies of methyl tert-butyl ether (MTBE) oxidation over Pt/Rh and Pd monolithic automotive catalysts were performed in a spinning basket flow reactor under atmospheric pressure. The reaction temperature was varied between 350 and 550 K, while MTBE concentration ranged from 10 to 500 ppm and oxygen concentration from 10 to 10 ppm. Various kinetic models have been tested in the analysis of the experimental data obtained in this work. The model that takes into account the surface reaction between dissociatively adsorbed reactants was found to yield the most successful fit and to be valid for both catalysts. According to this model, the activation energy of MTBE oxidation over Pt/Rh and Pd is estimated as 38 200 ± 110 J mol.
Bibliographic Details
Provide Feedback
Have ideas for a new metric? Would you like to see something else here?Let us know