PlumX Metrics
Embed PlumX Metrics

Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes: An entry to tetraorganosilicon reagents for the silicon-based cross-coupling reaction

Journal of the American Chemical Society, ISSN: 0002-7863, Vol: 127, Issue: 19, Page: 6952-6953
2005
  • 190
    Citations
  • 0
    Usage
  • 71
    Captures
  • 0
    Mentions
  • 0
    Social Media
Metric Options:   Counts1 Year3 Year

Metrics Details

Article Description

Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes, highly stable tetraorganosilicon reagents, are found to react with aryl and alkenyl iodides in the presence of a palladium catalyst and KCO as a base, significantly milder conditions compared with those ever reported for the silicon-based cross-coupling reactions. The reaction tolerates a wide range of functional groups, including silyl protectors, and allows a gram-scale synthesis to recover and reuse the silicon residue. Copyright © 2005 American Chemical Society.

Bibliographic Details

Nakao, Yoshiaki; Imanaka, Hidekazu; Sahoo, Akhila K; Yada, Akira; Hiyama, Tamejiro

American Chemical Society (ACS)

Chemical Engineering; Chemistry; Biochemistry, Genetics and Molecular Biology

Provide Feedback

Have ideas for a new metric? Would you like to see something else here?Let us know